Problems in cell design for the measurement of diffusion coefficients in the gas phase
Problems in cell design for the measurement of diffusion coefficients in the gas phase
复制标题
气相扩散系数测量的池设计问题
DOI：
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复制
发表时间：
1978
期刊：
影响因子：
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通讯作者：
P. Dunlop
中科院分区：
文献类型：
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作者：
K. Aoyagi;T. N. Bell;P. Dunlop
对于一个给定的二元系统的测量扩散系数之间的差异已被证明取决于所采用的电池设计的类型，尽管使用相同的基本测量技术。这些差异与混合过程中产生的热量有关，这是Dufour效应和非理想混合焓的结果。
Differences between the measured diffusion coefficients for a given binary system have been shown to depend on the type of cell design employed, despite use of the same basic measuring technique. These differences have been related to the heat generated in the mixing process, as a result of the Dufour effect and the non-ideal enthalpy of mixing.