Structure of copper(II) perchlorate hexahydrate.

Structure of copper(II) perchlorate hexahydrate.
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高氯酸铜(II)六水合物的结构。

DOI：
10.1107/s0108270189000818
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发表时间：
1989
期刊：
Acta crystallographica. Section C, Crystal structure communications
影响因子：
--
通讯作者：
Gerkin,RE
Gerkin,RE
中科院分区：
--
文献类型：
--
作者：
Gallucci,JC;Gerkin,RE

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Cu (C104) 2.6 H20, Mr= 370" 54, monoclinic, F21/c, a= 5.137 (1), b= 22.991~!,, c= 13.849 (2) A,/3= 90.66 (1), V= 1635.4 (4) Z= 6, Dx= 2.26 g cm-3, A (Mo K~)= 0-71069/~,/. i,= 26-44 cm-I, T= 296 K, F (000)= 1122, 2911 unique reflections having I> trz, R= 0.030. Each of the two inequivalent copper ions is coordinated by six water-molecule O atoms in a significantly distorted octa-hedral arrangement. Each of the three inequivalent but geometrically quite similar perchlorate groups is slightly distorted from regular tetrahedral geometry.