Polymerization in coordination nanospaces.
Polymerization in coordination nanospaces.
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DOI：
10.1002/asia.200600074
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发表时间：
2006-07
期刊：
影响因子：
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通讯作者：
T. Uemura;S. Horike;S. Kitagawa
中科院分区：
文献类型：
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作者：
T. Uemura;S. Horike;S. Kitagawa
在生物系统中优雅的聚合作用的启发下，在受限的人工纳米空间中合成聚合物是控制聚合物结构和设计明确的纳米结构的关键挑战。在这方面，多孔配位聚合物(PCPs)具有许多优点，如规则的孔道结构、可控的孔径、动态而灵活的孔道以及独特的表面电位和功能，可用于精确控制聚合和聚合物排列。本文从单体排列、聚合方法和聚合物结构控制这三个关键聚合过程的角度，介绍了聚碳酸酯纳米孔道聚合的最新进展，并论证了该聚合体系为何如此具有吸引力和应用前景。
Inspired by elegant polymerizations in biological systems, polymer synthesis in confined artificial nanospaces is a key challenge in the control of polymer structures and the design of well-defined nanostructures. In this regard, porous coordination polymers (PCPs) have a wide range of advantages, such as regular channel structures, controllable pore size, dynamic and flexible pores, and unique surface potentials and functionality, which can be utilized for precisely controlled polymerization and polymer arrangement. This Focus Review describes recent progress in polymerization in the nanochannels of PCPs and demonstrates why this polymerization system is so attractive and promising, from the viewpoints of three essential polymerization processes in PCPs, that is, monomer arrangement, polymerization methods, and control of polymer structure.