The ester dienolate [2,3]-Wittig rearrangement: Development, opportunities, and limitations
The ester dienolate [2,3]-Wittig rearrangement: Development, opportunities, and limitations
复制标题
酯二烯醇酯 [2,3]-Wittig 重排：发展、机遇和局限性
作者：
M. Hiersemann;Lars Abraham;A. Pollex
该帐户总结了酯二烯醇[2，3]-Wittig重排的发展作为一个多功能的合成工具，高度取代的3-烷氧羰基-3-羟基取代的1，5-己二烯的建设。此外，帐户提供了一个新的顺序周环反应采用1，5-己二烯可通过酯二烯醇[2，3]-Wittig重排的洞察。
The account summarizes the development of the ester dienolate [2,3]-Wittig rearrangement as a versatile synthetic tool for the construction of highly substituted 3-alkoxycarbonyl-3-hydroxy-substituted 1,5-hexadienes. Furthermore, the account provides an insight into a novel sequential pericyclic reaction employing the 1,5-hexadienes accessible through the ester dienolate [2,3]-Wittig rearrangement.