Pressure and Temperature Coefficients of Electrode Processes
Pressure and Temperature Coefficients of Electrode Processes
复制标题
电极过程的压力和温度系数
DOI：
10.1002/cite.330440423
复制
发表时间：
1972
影响因子：
1.9
通讯作者：
S. Hsieh
中科院分区：
文献类型：
--
作者：
G. Hills;S. Hsieh
虽然电极过程的理论描述主要涉及热力学函数，如能量、焓、熵和体积，但很少有实验确定这些重要的量。本文阐述了电极过程温度系数和压力系数实验值的理论意义。特别重要的是重视（1）的平衡表面过剩体积和熵和（2）与电荷转移反应的真实的和理想的活化参数。
Whilst the theoretical description of electrode processes is mainly concerned with thermodynamic functions such as energy, enthalpy, entropy and volume, very few experimental determinations of these important quantities have been made. This paper describes the theoretical significance of experimental values of the temperature and pressure coefficients of electrode processes. Particular importance is attached to (1) the equilibrium surface excess volumes and entropies and (2) the real and ideal activation parameters associated with charge-transfer reactions.