The Contribution of Microelectrodes to Electroanalytical Chemistry: From Reaction Mechanisms and Scanning Electrochemical Microscopy to Ocean Sensors
The Contribution of Microelectrodes to Electroanalytical Chemistry: From Reaction Mechanisms and Scanning Electrochemical Microscopy to Ocean Sensors
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微电极对电分析化学的贡献：从反应机理和扫描电化学显微镜到海洋传感器
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发表时间：
2010
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通讯作者：
G. Denuault
中科院分区：
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作者：
G. Denuault
微电极的出现开辟了新的研究领域，大大提高了电分析数据的质量。本文以作者的工作为例，简要介绍了微电极对电分析化学领域的贡献。几个基本的研究，从理论方法的发展，扫描电化学显微镜的耦合化学反应的机制和动力学的测定，被召回。大多数都涉及大量的数值模拟。一些应用研究说明了实验方法的发展，特别是纳米结构微电极的发展，以提高分析测量和传感的微电极响应的可靠性和质量。
The advent of microelectrodes has opened new areas of study and significantly improved the quality of electroanalytical data. Using examples from the author’s work, this brief review describes contributions made by microelectrodes to the field of electroanalytical chemistry. Several fundamental studies, ranging from the development of theoretical approaches for the scanning electrochemical microscope to the determination of the mechanism and kinetics of coupled chemical reactions, are recalled. Most involve a serious dose of numerical simulations. Several applied studies illustrate the development of experimental approaches, in particular the development of nanostructured microelectrodes, to improve the reliability and quality of the microelectrode response for analytical measurements and sensing.