Oxochloride Complexes of Rhenium
Oxochloride Complexes of Rhenium
复制标题
铼的氯氧化物配合物
DOI：
10.1139/v71-097
复制
发表时间：
1971
影响因子：
1.1
通讯作者：
C. Lock
中科院分区：
文献类型：
--
作者：
A. Guest;C. Lock
用Colton（2）描述的方法制备六氯环己烷的尝试没有成功。反应的产物总是不纯的四氧代四氯化物和五氧代四氯化物。化合物ReOCl 4 OPCl 3具有类似于离子ReOX4.L]−的结构，其中配位体呈假八面体排列，L反式位于氧代基团（3）。研究了ReOCl_4和ReOCl_4-OPCl_3与吡啶和2，2 ′-联吡啶的反应，提出了反应路线。合成了两种稳定的过氧氯与上述胺的配合物。
Attempts to prepare rhenium hexachloride by the method described by Colton (2) have been unsuccessful. The products of the reaction were always impure rhenium oxotetrachloride and rhenium pentachloride. A compound of rhenium(VI), ReOCl4OPCl3, is shown to have a structure analogous to that of rhenium(V) ions [ReOX4.L]− in which the ligands are in a pseudooctahedral arrangement with L trans to the oxo-group (3). Reactions of ReOCl4 and ReOCl4-OPCl3 with pyridine and 2,2′-dipyridyl are described, and a scheme is proposed for the reactions of the products. Two stable complexes of perrhenyl chloride with the above amines have been obtained.