Determination of Henry’s law constant of halocarbons in seawater and analysis of sea-to-air flux of iodoethane (C2H5I) in the Indian and Southern oceans based on partial pressure measurements

Determination of Henry’s law constant of halocarbons in seawater and analysis of sea-to-air flux of iodoethane (C2H5I) in the Indian and Southern oceans based on partial pressure measurements
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基于分压测量测定海水中卤化碳的亨利定律常数并分析印度洋和南大洋中碘乙烷 (C2H5I) 的海气通量

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发表时间:
2011
期刊:
影响因子:
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通讯作者:
Y. Yokouchi
Y. Yokouchi
中科院分区:
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文献类型:
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作者:
A. Ooki;Y. Yokouchi

文献摘要

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式中u为风速,Sc为施密特数。几位研究者报道了氯氟化碳CFC-11和CFC12(用作追踪以前暴露于大气的深海水历史的示踪剂)的KH值作为海水温度和盐度的函数(Hunter-Smith等人,1983年;Warner和Weiss, 1985年;Wisegarver和Cline, 1985年),也报道了海水中某些卤代烃(例如CH3I、CH2Br2和CH2ClI)的KH值(HunterSmith等人,1983年;Elliott和Rowland, 1993年;戈塞仍,1987;Moore et al., 1995;摩尔,2000)。然而,海水中C2H5I和C5H8的KH值作为海水中卤代烃亨利定律常数的测定和印度洋和南部海洋中碘乙烷(C2H5I)的海气通量分析的函数
where u is the wind speed and Sc is the Schmidt number. The KH values for chlorofluorocarbons CFC-11 and CFC12 (which are used as tracers to track the history of deep seawater previously exposed to the atmosphere) as functions of seawater temperature and salinity have been reported by several investigators (Hunter-Smith et al., 1983; Warner and Weiss, 1985; Wisegarver and Cline, 1985), and values for some halocarbons (e.g., CH3I, CH2Br2, and CH2ClI) in seawater have also been reported (HunterSmith et al., 1983; Elliott and Rowland, 1993; Gossett, 1987; Moore et al., 1995; Moore, 2000). However, the KH values of C2H5I and C5H8 in seawater as functions of Determination of Henry’s law constant of halocarbons in seawater and analysis of sea-to-air flux of iodoethane (C2H5I) in the Indian and Southern oceans based on partial pressure measurements