Organic Inhibitors of Corrosion, Aliphatic Amines
Organic Inhibitors of Corrosion, Aliphatic Amines
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DOI：
10.1021/ie50314a004
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发表时间：
1936-02
影响因子：
--
通讯作者：
C. Mann;B. E. Lauer;Clifford T. Hultin
中科院分区：
文献类型：
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作者：
C. Mann;B. E. Lauer;Clifford T. Hultin
| VER自从Speller（28）报道了使用含有有机缓蚀剂的盐酸来清洗严重结垢的水管以来，人们对有机缓蚀剂的研究越来越感兴趣。早在1872年，Maran-goni和Stephanelli（21）就指出精油可以有效降低酸对铁的作用速度。1919年的一项专利（7A）涉及使用粗蒽和油残渣，1920年的另一项专利（17）涉及使用漆树提取物用于酸洗浴。醛的使用（6，7，13，16，18），有机碱（10，19，22，23，26，27，32）的化合物，以及含有氮、砷、磷、硫、硒的有机化合物，以及其它复杂的合成或天然有机物质和副产物（2、5、8、11、12、25、29、30、31和大约70个美国、英国和德国专利）已被提出作为缓蚀剂或进行了研究。人们普遍认为，这些缓蚀剂可以防止铁的阴极区的氢排放，从而消除腐蚀。在这方面，正如Speller（27）所建议的那样，它们表现得像催化剂。Speller（27）、罗兹和库恩（23）以及其他人（S，9，14，32）认为，抑制剂形成一个覆盖层或膜，防止氢的释放。根据Isgarishev和Bergmann（19），R. Audubert（4），Chappell，Roetheli和McCarthy（9）和Warner（32），
| VER since Speller (28) reported the use of hydrochloric acid containing an organic inhibitor for cleaning out badly scaled water pipes, there has been an increasing interest in the study of organic inhibitors of corrosion. As early as 1872 Maran-goni and Stephanelli (21) stated that essential oils were effective in reducing the speed of action of acids on iron. One patent (7A) in 1919 covers the use of crude anthracene and oil residues, and another in 1920 (17) pertains to the use of extract of sumac for pickling baths. The use of aldehydes (6, 7, 13, 16, 18), organic bases (10, 19, 22, 23, 26, 27, 32), and organic compounds containing nitrogen, arsenic, phosphorus, sulfur, selenium, and other complex synthetic or natural organic substances and by-products (2, 5, 8, 11, 12, 25, 29, 30, 31, and some seventy United States, British, and German patents) have been proposed as inhibitors or have been inves-tigated.A number of explanationshave been offered as to the mechanism of protection of iron against the corroding action of acids by organic inhibitors. It is generally agreed that these inhibitors prevent thedischarge of hydrogen on the cathodic areas of iron, thus eliminating corrosion. In this respect they behave like catalysts as suggested by Speller (27). Speller (27), Rhodes and Kuhn (23), and others (S, 9, 14, 32) suggest that the inhibitors form a blanketing layer or film which prevents the discharge of the hydrogen. Such a layer will form if the inhibitor is a properly charged colloid according to Isgarishev and Bergmann (19), R. Audubert (4), Chappell, Roetheli, and McCarthy (9), and Warner (32),