A brief review of continuous models for ionic solutions: the Poisson–Boltzmann and related theories

A brief review of continuous models for ionic solutions: the Poisson–Boltzmann and related theories
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离子溶液连续模型的简要回顾:泊松玻尔兹曼及相关理论

DOI:
10.1088/1572-9494/ab8a23
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发表时间:
2020-01
影响因子:
3.1
通讯作者:
Yanting Wang
Yanting Wang
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Mao Su;Yanting Wang

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泊松-玻尔兹曼(PB)理论是连续描述带电系统的重要理论模型之一。然而,它的缺点是忽略了离子的相关性,这阻碍了它在除极稀系统以外的更一般的带电系统中的适用性。因此,一些修正版本的PB理论发展有效地包括离子相关性。本文从离子溶液的应用出发,综述了原有的PB理论及其衍生理论,包括场论方法、相关增强PB模型、Outhwaite-Bhuiyan修正PB理论和平均场理论,并分析了它们的优点和局限性。
The Poisson-Boltzmann (PB) theory is one of the most important theoretical models describing charged systems continuously. However, it suffers from neglecting ion correlations, which hinders its applicability to more general charged systems other than extremely dilute ones. Therefore, some modified versions of the PB theory are developed to effectively include ion correlations. Focused on their applications to ionic solutions, the original PB theory and its variances, including the field-theoretic approach, the correlation-enhanced PB model, the Outhwaite-Bhuiyan modified PB theory and the mean field theories, are briefly reviewed in this paper with the diagnosis of their advantages and limitations.
DOI: 10.1063/1.1669709
发表时间: 1968-05
影响因子: 4.4
作者:
F. Stillinger;R. Lovett
通讯作者: F. Stillinger;R. Lovett
DOI: 10.1039/f29807601388
发表时间: 1980
期刊: Journal of the Chemical Society, Faraday Transactions
影响因子: --
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DOI: 10.1039/b316098j
发表时间: 2004-07
影响因子: 3.3
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通讯作者: L. B. Bhuiyan;C. W. Outhwaite
DOI: 10.1016/s1383-8121(06)80005-9
发表时间: 1995
期刊: --
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作者:
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