Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.
Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.
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DOI：
10.1002/anie.200805566
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发表时间：
2009
期刊：
影响因子：
--
通讯作者：
Russo L
中科院分区：
文献类型：
--
作者：
Alborés P;Carrella LM;Clegg W;García-Alvarez P;Kennedy AR;Klett J;Mulvey RE;Rentschler E;Russo L
棋盘和图形代表了一种特殊的反应，其中不同的低极性金属可以直接金属化芳烃时，他们被带到正确的位置。在皇后（钠）和骑士（铬或铁）的组合中，骑士（通常是较弱的棋子）有可能在这场元素象棋比赛中对国王（苯）进行直接致命的打击。
The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (usually the weaker piece) to make a direct deadly hit on the king (benzene) in this game of elemental chess.