X-ray absorption spectra of ruthenium L edges in hexaammineruthenium trichloride

X-ray absorption spectra of ruthenium L edges in hexaammineruthenium trichloride
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三氯化六氨钌中钌L边的X射线吸收光谱

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发表时间:
1983
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通讯作者:
T. Sham
T. Sham
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文献类型:
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作者:
T. Sham

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用同步辐射X射线吸收光谱研究了钌(Ru(NH/sub 3/)/sub 6/)Cl/sub 3/的L边吸收谱。研究发现,Ru L边呈现出配位场和自旋轨道效应的白色特征线。局部对称性的基础上的数据和复杂的电子构型的分析产生3.93 eV的10 Dq值。
X-ray absorption spectra of ruthenium L edges of (Ru(NH/sub 3/)/sub 6/)Cl/sub 3/ have been obtained with synchrotron radiation. It is found that Ru L edges exhibit white lines characteristic of ligand-field and spin-orbit effects. Analysis of the data on the basis of local symmetry and the electronic configuration of the complex yields a 10Dq value of 3.93 eV.