X-ray absorption spectra of ruthenium L edges in hexaammineruthenium trichloride
X-ray absorption spectra of ruthenium L edges in hexaammineruthenium trichloride
复制标题
三氯化六氨钌中钌L边的X射线吸收光谱
DOI:
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发表时间:
1983
期刊:
影响因子:
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通讯作者:
T. Sham
中科院分区:
文献类型:
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作者:
T. Sham
X-ray absorption spectra of ruthenium L edges of (Ru(NH/sub 3/)/sub 6/)Cl/sub 3/ have been obtained with synchrotron radiation. It is found that Ru L edges exhibit white lines characteristic of ligand-field and spin-orbit effects. Analysis of the data on the basis of local symmetry and the electronic configuration of the complex yields a 10Dq value of 3.93 eV.