SYNTHETIC STUDIES RELEVANT TO BIOSYNTHETIC RESEARCH ON VITAMIN-B12 .7. SYNTHESIS OF (+/-)-BONELLIN DIMETHYL ESTER

SYNTHETIC STUDIES RELEVANT TO BIOSYNTHETIC RESEARCH ON VITAMIN-B12 .7. SYNTHESIS OF (+/-)-BONELLIN DIMETHYL ESTER
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DOI:
10.1039/p19880001569
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发表时间:
1988-06-01
期刊:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
影响因子:
--
通讯作者:
FOOKES, CJR
FOOKES, CJR
中科院分区:
其他
文献类型:
--
作者:
BATTERSBY, AR;DUTTON, CJ;FOOKES, CJR

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采用合理的光化学方法合成了外消旋的绿色海洋色素博内林的二甲酯。这种生物活性色素的两个丙酸酯残基以不同的形式合成引入,这为合成天然存在的Bonellin氨基酸衍生物开辟了道路。
The dimethyl ester of the green marine pigment, bonellin, has been synthesized in racemic form by a rational photochemical route. The two proprionate residues of this biologically active pigment have been introduced synthetically in differentiate form which opens the ways to the synthesis of the naturally occurring amino acid derivatives of bonellin.