Synthesis and Reactivity of Cobalt?Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen
Synthesis and Reactivity of Cobalt?Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen
复制标题
带有阴离子PCP型钳配体的钴二氮配合物的合成及其催化二氮生成甲硅烷胺的反应活性
DOI：
10.1021/acs.inorgchem.2c00234
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发表时间：
2022
影响因子：
4.6
通讯作者：
Nishibayashi Yoshiaki
中科院分区：
文献类型：
--
作者：
Kuriyama Shogo;Wei Shenglan;Tanaka Hiromasa;Konomi Asuka;Yoshizawa Kazunari;Nishibayashi Yoshiaki
合成并表征了一系列含阴离子4-取代苯基PCP钳形配体的钴（I）-二氮配合物。这些络合物用作在环境反应条件下由二氮形成甲硅烷基胺的高效催化剂，以催化剂的钴原子计产生高达371当量的甲硅烷基胺。
A series of cobalt(I)–dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to produce up to 371 equiv of silylamine based on the cobalt atom of the catalyst.