ALLYLIC AMINATION OF OLEFINS AND ACETYLENES BY IMIDO SELENIUM-COMPOUNDS
ALLYLIC AMINATION OF OLEFINS AND ACETYLENES BY IMIDO SELENIUM-COMPOUNDS
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DOI：
10.1021/ja00417a062
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发表时间：
1976-01-01
影响因子：
15
通讯作者：
DIETRICH, CO
中科院分区：
文献类型：
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作者：
SHARPLESS, KB;HORI, T;DIETRICH, CO
在我们最近关于用亚胺锇化合物邻氧胺化烯烃的报告中，我们提出这可能是一类新的反应的第一个例子，这些反应涉及已知的氧插入过程的氮和碳类似物。通过发现二氧化硒(2)2的偶氮类似物(1)影响烯烃的烯丙基胺化，我们现在将这一概念扩展到主基团氧化剂。
In our recent report1 on the vicinal oxyamination of ole-fins by imido osmium compounds we suggested that it might be the first example of a new class of reactions involving nitrogen and carbon analogues of known oxygen insertion processes. By finding that aza analogues (1) of sele-nium dioxide (2) 2 effect allylic amination of olefins, we have now extended this concept to a main group oxidant.