Controlling the assembly of cyclotriveratrylene-derived coordination cages.
Controlling the assembly of cyclotriveratrylene-derived coordination cages.
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DOI：
10.1039/c5cc03071d
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发表时间：
2015-07
影响因子：
4.9
通讯作者：
James J. Henkelis;M. Hardie
中科院分区：
文献类型：
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作者：
James J. Henkelis;M. Hardie
综述了环三戊四烯衍生配位笼的研究进展。配体功能化的环三戊二烯（CTV）衍生物与一系列金属阳离子自组装，形成配位笼、聚合物和拓扑结构，如[2]链烷和自纠缠立方体。通过观察表面活性剂结合和单晶对单晶（SCTSC）对小分子客体的吸收，增加了对其自组装的控制，可以控制和预测形成定义良好的配位笼，用于主客体和识别化学。
A review of the emerging field of cyclotriveratrylene-derived coordination cages is presented. Ligand-functionalised cyclotriveratrylene (CTV) derivatives self-assemble with a range of metal cations to afford coordination cages, polymers and topologically non-trivial constructs, such as [2]catenanes and a self-entangled cube. Increased control over their self-assembly allows for the controlled and predictable formation of well-defined coordination cages for application in host-guest and recognition chemistry, with surfactant binding and single-crystal-to-single-crystal (SCTSC) uptake of small-molecule guests being observed.