A Highly Diastereo- and Enantioselective Hg(II)-Catalyzed Cyclopropanation of Diazooxindoles and Alkenes
A Highly Diastereo- and Enantioselective Hg(II)-Catalyzed Cyclopropanation of Diazooxindoles and Alkenes
复制标题
高度非对映和对映选择性 Hg(II) 催化重氮杂吲哚和烯烃的环丙烷化反应
DOI：
10.1021/ol302998m
复制
发表时间：
2013-01-04
期刊：
影响因子：
5.2
通讯作者：
Zhou, Jian
中科院分区：
文献类型：
--
作者：
Cao, Zhong-Yan;Zhou, Feng;Zhou, Jian
首次报道了Hg（II）催化重氮试剂和烯烃的环丙烷化反应，实现了螺环丙基羟基吲哚类化合物的高度非对映和对映选择性合成。
It is reported for the first time that Hg(II) can catalyze the cyclopropanation of diazo reagents and alkenes, which contributes to the unprecedented highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles.