An activation-free method for preparing microporous carbon by the pyrolysis of poly(vinylidene fluoride)

An activation-free method for preparing microporous carbon by the pyrolysis of poly(vinylidene fluoride)
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一种聚偏二氟乙烯热解制备微孔碳的免活化方法

DOI:
10.1016/j.carbon.2010.04.011
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发表时间:
2010-08-01
期刊:
影响因子:
10.9
通讯作者:
Yang, Yusheng
Yang, Yusheng
中科院分区:
材料科学2区
文献类型:
--
作者:
Xu, Bin;Hou, Shanshan;Yang, Yusheng

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介绍了一种不经活化或其它任何附加步骤,在N2气氛下高温热解聚偏氟乙烯(PVDF)制备微孔炭的简单方法。PVDF衍生碳的产率为35.0%。其比表面积达1012 m2/g,孔容为0.41 cm 3/g。碳是微孔的,在0.55 nm处具有单峰孔径分布。(C)2010爱思唯尔有限公司版权所有。
A simple method for the preparation of microporous carbon was presented by pyrolyzing poly(vinylidene fluoride) (PVDF) at high temperature under N(2) atmosphere without activation or any other additional processes. The yield of PVDF-derived carbon is 35.0%. Its specific surface area reaches 1012 m(2) g with a pore volume of 0.41 cm(3) g(-1). The carbon is microporous with unimodal pore size distribution at 0.55 nm. (C) 2010 Elsevier Ltd. All rights reserved.