Aerobic oxidative amination of unactivated alkenes catalyzed by palladium
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium
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DOI：
10.1021/ja0433020
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发表时间：
2005-03-09
影响因子：
15
通讯作者：
Stahl, SS
中科院分区：
文献类型：
--
作者：
Brice, JL;Harang, JE;Stahl, SS
未活化烷基烯烃的钯催化氧化胺化的第一个例子已经确定。为了成功，这些反应必须在无助催化剂的条件下进行，其中涉及钯催化剂的直接分子氧耦合转换。降冰片烯和其他环烯烃的氧化胺化产物暗示了顺式氨基钯化机制。
The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate acis-aminopalladation mechanism.