Ordered Supramolecular Assembly of Porphyrin–Fullerene Composites on Nanostructured SnO2 Electrodes
Ordered Supramolecular Assembly of Porphyrin–Fullerene Composites on Nanostructured SnO2 Electrodes
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DOI：
10.1002/adma.200600312
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发表时间：
2006-10
影响因子：
29.4
通讯作者：
S. Kang;T. Umeyama;Masahito Ueda;Y. Matano;H. Hotta;K. Yoshida;S. Isoda;M. Shiro;H. Imahori
中科院分区：
文献类型：
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作者：
S. Kang;T. Umeyama;Masahito Ueda;Y. Matano;H. Hotta;K. Yoshida;S. Isoda;M. Shiro;H. Imahori
c60和卟啉在sno2电极上组装成有序的超分子复合结构，产生非常高的光电流。在卟啉环上介苯基的中间位置上简单的甲氧基取代导致了如图所示的有序的堆叠排列，在一维卟啉链和二维c60片上具有独立的电子和空穴传递路径。
Very high photocurrent generation is seen for an ordered supramolecular composite structure of C 60 and porphyrin assembled on SnO 2 electrodes. The simple substitution of methoxy groups at the meta positions of the meso‐phenyl groups on the porphyrin ring leads to the ordered stacking arrangement shown in the figure, with separate electron and hole transport paths along the 1D porphyrin chains and 2D C 60 sheets.