Preparation of Group-6 Metal(0) Carbonyl Complexes of Chelate Type Containing Diphosphinidenecyclobutene as a Bidentate Ligand

Preparation of Group-6 Metal(0) Carbonyl Complexes of Chelate Type Containing Diphosphinidenecyclobutene as a Bidentate Ligand
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二膦亚环丁烯双齿配体螯合型第6族金属(0)羰基配合物的制备

DOI:
10.1246/cl.1991.2079
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发表时间:
1991
期刊:
影响因子:
1.6
通讯作者:
M. Yoshifuji
M. Yoshifuji
中科院分区:
化学4区
文献类型:
--
作者:
Kozo Toyota;Katsuya Tashiro;M. Yoshifuji

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使(E,E)-3,4-双(2,4,6-三叔丁基苯基亚膦基)-1,2-双(三甲基甲硅烷基)环丁烯与第6族金属(0)羰基化合物反应,得到稳定的螯合型四羰基络合物,其中金属是铬、钼和钨。
(E,E)-3,4-Bis(2,4,6-tri-t-butylphenylphosphinidene)-1,2-bis(trimethylsilyl)cyclobutene was allowed to react with the group-6 metal(0) carbonyls to give stable tetracarbonyl complexes of chelate type, where the metal is chromium, molybdenum, and tungsten.