Coordination polymers formed by Bi(SC6F5)3 with multidentate polypyridyl ligands
Coordination polymers formed by Bi(SC6F5)3 with multidentate polypyridyl ligands
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Bi(SC6F5)3 与多齿聚吡啶配体形成的配位聚合物
DOI：
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发表时间：
2004
期刊：
影响因子：
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通讯作者：
T. Podesta
中科院分区：
文献类型：
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作者：
J. Charmant;A. H. M. M. Jahan;N. C. Norman;A. Orpen;T. Podesta
硫醇铋（III）Bi（SC 6 F5）3和双（三氟甲基）硫代磷酸之间的反应（4-吡啶基）配体4，4 ′-联吡啶（4，4 ′-bipy），1，2-bis（4-吡啶基）乙烷或反式-1，2-双（4-吡啶基）乙烯（四氢呋喃）或DMF（二甲基甲酰胺）溶液结晶后得到一维聚合物结构{[Bi（SC 6 F5）3（thf）（4，4 ′-bipy）]}∞、{[Bi（SC_6 F_5）_3（dmf）{1，2-双（4-吡啶基）乙烷}]}∞和{[Bi（SC_6 F_5）_3（thf）{trans-1，2-双（4-吡啶基）乙烯}].thf}∞。当三-4-吡啶基配体2，4，6-三使用（4-吡啶基）-1，3，5-三嗪，即{[Bi（SC 6 F5）3{2，4，6-三（4-吡啶基）-1，3，5-三嗪}]}∞，而与2，4，6-三（2-吡啶基）-1，3，5-三嗪则得到单体配合物[Bi（SC 6 F5）3{2，4，6-三（2-吡啶基）-1，3，5-三嗪}]。
The reaction between the bismuth(III) thiolate Bi(SC6F5)3 and the bis(4-pyridyl) ligands 4,4′-bipyridyl (4,4′-bipy), 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene in either thf (tetrahydrofuran) or dmf (dimethylformamide) solution affords, after crystallisation, the one-dimensional polymeric structures {[Bi(SC6F5)3(thf)(4,4′-bipy)]}∞, {[Bi(SC6F5)3(dmf){1,2-bis(4-pyridyl)ethane}]}∞ and {[Bi(SC6F5)3(thf){trans-1,2-bis(4-pyridyl)ethene}].thf}∞. A related one-dimensional polymeric structure is observed when the tris-4-pyridyl ligand 2,4,6-tris(4-pyridyl)-1,3,5-triazine is employed, namely {[Bi(SC6F5)3{2,4,6-tris(4-pyridyl)-1,3,5-triazine}]}∞, whereas with 2,4,6-tris-2-pyridyl-1,3,5-triazine, a monomeric complex [Bi(SC6F5)3{2,4,6-tris(2-pyridyl)-1,3,5-triazine}] is obtained.