First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers
First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers
复制标题
2-三氟甲基丙烯酸在水中的首次自由基均聚以及所得均聚物的降解研究
DOI：
10.1039/c3cc42395f
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发表时间：
2013
影响因子：
4.9
通讯作者：
Bruno Ameduri
中科院分区：
文献类型：
--
作者：
Yogesh Patil;Hisao Hori;Hirotaka Tanaka;Takehiko Sakamoto;Bruno Ameduri
Na2S2O8在水中引发2-三氟甲基丙烯酸（MAF）的自由基均聚反应，在pH的影响下，生成了原始水溶性表面活性剂，并对其分解进行了研究。在80℃时，MAF的增殖速率常数与终止速率常数kp2/kte的平方值为4 × 10−3 l mol−1 s−1。
The radical homopolymerisation of 2-trifluoromethacrylic acid (MAF) initiated by Na2S2O8 in water, under the influence of pH, led to original water soluble surfactants, the decomposition of which was investigated. The value of the square of the propagation rate constant to the termination rate constant, kp2/kte, of MAF was 4 × 10−3 l mol−1 s−1 at 80 °C.