Metal-Free Arene and Heteroarene Borylation Catalyzed by Strongly Electrophilic Bis-boranes
Metal-Free Arene and Heteroarene Borylation Catalyzed by Strongly Electrophilic Bis-boranes
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DOI：
10.1002/chem.201701771
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发表时间：
2017-09-07
影响因子：
4.3
通讯作者：
Erker, Gerhard
中科院分区：
文献类型：
--
作者：
Liu, Yun-Lin;Kehr, Gerald;Erker, Gerhard
双螯合双硼烷4和5分别具有强亲电性B(C6F5)(2)和B（C6F5）基团，是芳烃和杂芳烃硼化反应的有效催化剂。硼化反应在温和的条件下进行，释放出二氢。
The geminal chelate bis-borylalkanes 4 and 5 featuring strongly electrophilic B(C6F5)(2) and B(C6F5) groups, respectively, serve as efficient catalysts for the borylation of arenes and heteroarenes. The borylation reactions proceed under mild conditions with liberation of dihydrogen.