Two-step modulation of ion recognition using a bis(saloph)-macrocyclic host having a 24-crown-8-like cavity
Two-step modulation of ion recognition using a bis(saloph)-macrocyclic host having a 24-crown-8-like cavity
复制标题
使用具有 24-crown-8-like 空腔的双（saloph）-大环主体进行离子识别的两步调制
DOI：
10.1039/c7cc02641b
复制
发表时间：
2017
影响因子：
4.9
通讯作者：
and Shigehisa Akine
中科院分区：
文献类型：
--
作者：
Yoko Sakata;Seiya Kobayashi;and Shigehisa Akine
通过高效的两步转化新合成的大环配体H4L2，实现了阳离子结合亲和力的精确调制，该配体具有24冠8状腔和两个saloph基团。H4L2转化为L2Ni2后，对Cs+的结合亲和力提高了120倍。电化学还原后的L2Ni2进一步提高了3个数量级的识别能力。
Precise modulation of cation binding affinity was accomplished by the efficient two-step conversion of a newly synthesized macrocyclic ligand H4L2 having a 24-crown-8-like cavity and two saloph moieties. The conversion of H4L2 into L2Ni2 resulted in a 120-fold enhancement in the binding affinity towards Cs+. The electrochemical reduction of L2Ni2 further enhanced the recognition ability by 3 orders of magnitude.