Velocity map imaging in time of flight mass spectrometry
Velocity map imaging in time of flight mass spectrometry
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DOI:
10.1063/1.3036978
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发表时间:
2008-12-01
影响因子:
1.6
通讯作者:
Nomerotski, A.
中科院分区:
文献类型:
--
作者:
Brouard, M.;Campbell, E. K.;Nomerotski, A.
A new variation on time of flight mass spectrometry is presented, which uses a fast framing charge coupled device camera to velocity map image multiple product masses in a single acquisition. The technique is demonstrated on two photofragmentation processes, those of CS(2) and CH(3)S(2)CH(3) (dimethyldisulfide) at a photolysis wavelength of 193 nm. In both cases, several mass fragments are imaged simultaneously, and speed distributions and anisotropy parameters are extracted that are comparable to those obtained by imaging each fragment separately in conventional velocity map imaging studies.