Hybrid CuO-TiO2-xNx Hollow Nanocubes for Photocatalytic Conversion of CO2 into Methane under Solar Irradiation

Hybrid CuO-TiO2-xNx Hollow Nanocubes for Photocatalytic Conversion of CO2 into Methane under Solar Irradiation
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DOI:
10.1002/anie.201108936
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发表时间:
2012-01-01
影响因子:
16.6
通讯作者:
Schaak, Raymond E.
Schaak, Raymond E.
中科院分区:
化学1区
文献类型:
--
作者:
In, Su-Il;Vaughn, Dimitri D., II;Schaak, Raymond E.

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产生甲烷的中空纳米立方体:通过首先将TiO(2)沉积到Cu(3)N纳米立方体模板上,然后在空气中加热以将Cu(3)N氧化为CuO,同时将氮气引入TiO(2)中,合成了混合CuO-TiO(2-x)N(x)中空纳米立方体。纳米结构的CuO-TiO(2-x)N(x)材料在太阳光照射下将CO(2)光催化转化为甲烷。
Methane-producing hollow nanocubes: Hybrid CuO-TiO (2-x) N (x) hollow nanocubes have been synthesized by first depositing TiO (2) onto Cu (3) N nanocube templates, then heating in air to oxidize the Cu (3) N to CuO while concomitantly incorporating nitrogen into the TiO (2). The nanostructured CuO-TiO (2-x) N (x) material photocatalytically converts CO (2) into methane under solar irradiation.