Parahydrogen-induced polarization (PHIP) in heterogeneous hydrogenation over bulk metals and metal oxides

Parahydrogen-induced polarization (PHIP) in heterogeneous hydrogenation over bulk metals and metal oxides
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DOI:
10.1039/c3cc44939d
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发表时间:
2014-01-01
影响因子:
4.9
通讯作者:
Koptyug, Igor V.
Koptyug, Igor V.
中科院分区:
化学2区
文献类型:
--
作者:
Kovtunov, Kirill V.;Barskiy, Danila A.;Koptyug, Igor V.

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结果表明,一般来说,观察 PHIP 对金属的影响不需要支撑物的存在。此外,某些金属氧化物在没有负载金属的情况下可以产生 PHIP 效应。用于多相生产 PHIP 的新的有前景的催化剂已经被确定。
The results show that, in general, observation of PHIP effects on metals does not require the presence of a support. In addition, certain metal oxides can produce PHIP effects in the absence of a supported metal. The new promising catalysts for producing PHIP heterogeneously have been identified.