Mass spectrometry in organic and bio‐organic catalysis: Using thermochemical properties to lend insight into mechanism
Mass spectrometry in organic and bio‐organic catalysis: Using thermochemical properties to lend insight into mechanism
复制标题
有机和生物有机催化中的质谱分析：利用热化学性质深入了解机理
DOI：
10.1002/mas.21797
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发表时间：
2022
影响因子：
6.6
通讯作者：
Lee, Jeehiun K.
中科院分区：
文献类型：
--
作者：
Hinz, Damon J.;Zhang, Lanxin;Lee, Jeehiun K.
在这篇综述中，我们讨论了气相实验为中心的酸度和质子亲和力的基板，是有用的理解催化机制的测量。审查分为两个部分。第一个涵盖有机催化的例子，而第二个侧重于生物催化。的效用的气相酸度和碱度值贷款洞察催化机制的突出。
In this review, we discuss gas phase experimentation centered on the measurement of acidity and proton affinity of substrates that are useful for understanding catalytic mechanisms. The review is divided into two parts. The first covers examples of organocatalysis, while the second focuses on biological catalysis. The utility of gas phase acidity and basicity values for lending insight into mechanisms of catalysis is highlighted.