Engineering carbene rearrangements in crystals: from molecular information to solid-state reactivity.
Engineering carbene rearrangements in crystals: from molecular information to solid-state reactivity.
复制标题
晶体中卡宾重排的工程设计：从分子信息到固态反应性。
DOI：
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发表时间：
2003
影响因子：
18.3
通讯作者：
M. Garcia‐Garibay
中科院分区：
文献类型：
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作者：
M. Garcia‐Garibay
尽管受到严格限制，晶体中的反应已经提供了一些最令人印象深刻的化学控制例子，并为详细的机理研究提供了理想的介质。然而，为了充分利用它们的潜力并避免它们的缺点，需要一种系统的方法来可靠地设计晶体中的反应。为此，已经通过涉及卡宾重排的反应探索了基于分子水平上包含的结构和能量信息的策略。
Although severely restricted, reactions in crystals have delivered some of the most impressive examples of chemical control and provided an ideal medium for detailed mechanistic studies. However, to take full advantage of their potential and avoid their shortcomings, a systematic approach for the reliable design of reaction in crystals is required. To that end, strategies based on structural and energetic information contained at the molecular level have been explored with reactions involving carbene rearrangements.