1,4-Phenylene-bridged Subporphyrin-Porphyrin Dyad, Triad, and Tetrad
1,4-Phenylene-bridged Subporphyrin-Porphyrin Dyad, Triad, and Tetrad
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DOI：
10.1246/cl.2009.206
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发表时间：
2009-03-05
影响因子：
1.6
通讯作者：
Osuka, Atsuhiro
中科院分区：
文献类型：
--
作者：
Inokuma, Yasuhide;Hayashi, Shin-ya;Osuka, Atsuhiro
通过meso-（4-溴苯基）取代亚卟啉2和5-频哪醇硼基卟啉3的Suzuki-Miyaura交叉偶联反应，制备了1，4-亚苯基桥联亚卟啉-卟啉杂化分子.在所有的混合模型检查，从亚卟啉部分的卟啉部分的分子内能量转移有效地进行。
1,4-Phenylene-bridged subporphyrin-porphyrin hybrid molecules were prepared by the Suzuki-Miyaura cross coupling reaction of meso-(4-bromophenyl)-substituted subporphyrin 2 and 5-pinacolateboryl porphyrin 3. In all hybrid models examined, intramolecular energy transfer from the subporphyrin moiety to the porphyrin moieties proceeds efficiently.