In situ cryo-crystallization of fluorinated amines: A comparative study of cooperative intermolecular interactions involving ordered and disordered fluorine
In situ cryo-crystallization of fluorinated amines: A comparative study of cooperative intermolecular interactions involving ordered and disordered fluorine
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DOI：
10.1021/cg060053d
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发表时间：
2006-04-01
影响因子：
3.8
通讯作者：
Row, TNG
中科院分区：
文献类型：
--
作者：
Chopra, D;Thiruvenkatam, V;Row, TNG
低温晶体结构的4-氟苯胺和2-氟苯胺，确定以下从液体中的原位晶体生长，揭示了强氢键和弱分子间相互作用的重要性，涉及氟产生不同的包装图案的结晶固体中的同分异构分子。
The low-temperature crystal structures of 4-fluoroaniline and 2-fluoroaniline, determined following in situ crystal growth from the liquid, reveal the importance of both strong hydrogen bonds and weak intermolecular interactions involving fluorine generating different packing motifs in the crystalline solid in the isomeric molecules.