Unexpected C–O Bond Cleavage by a Copper–Phosphido Compound
Unexpected C–O Bond Cleavage by a Copper–Phosphido Compound
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DOI：
10.3390/m1659
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发表时间：
2023-06
期刊：
影响因子：
0.6
通讯作者：
Steven G Dannenberg;R. Waterman
中科院分区：
文献类型：
--
作者：
Steven G Dannenberg;R. Waterman
甲醇铜化合物IPrCuOMe是由IPrCuPPh2与丙烯酸甲酯反应生成的。对反应混合物中的醇盐产物进行了波谱和结构表征。这种C-O键断裂反应可能依赖于IPrCuPPh2的铜-磷键的亲核性。
Copper methoxide compound IPrCuOMe was unexpectedly formed in a reaction of IPrCuPPh2 with methyl acrylate. The alkoxide product was identified from the reaction mixture spectroscopically and structurally characterized. This C–O bond cleavage reaction likely depends on nucleophilicity of the Cu–P bond of IPrCuPPh2.