Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters:: efficient synthesis of β-boryl-α,β-ethylenic esters

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters:: efficient synthesis of β-boryl-α,β-ethylenic esters
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DOI:
10.1039/b716697d
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发表时间:
2008-01-01
影响因子:
4.9
通讯作者:
Yun, Jaesook
Yun, Jaesook
中科院分区:
化学2区
文献类型:
--
作者:
Lee, Ji-Eon;Kwon, Jisook;Yun, Jaesook

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研究了铜催化双硼与α, β -乙基酯的加成反应,在温和的反应条件下以高产率制备了相应的β -硼化α, β -乙基酯。
The efficient copper-catalyzed addition reaction of bis(pinacolato) diboron to alpha,beta-acetylenic esters has been developed, which produces the corresponding beta-borylated-alpha,beta-ethylenic esters in high yields under mild reaction conditions.