White light-emitting diodes based on an all-phosphorescent supramolecular polymer

White light-emitting diodes based on an all-phosphorescent supramolecular polymer
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基于全磷光超分子聚合物的白色发光二极管

DOI:
10.1039/c5py00832h
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发表时间:
2015-08
期刊:
影响因子:
4.6
通讯作者:
Cao Yong
Cao Yong
中科院分区:
化学2区
文献类型:
--
作者:
Liang Aihui;Dong Sheng;Zhu Xiuhui;Huang Fei;Cao Yong

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Novel white light-emitting supramolecular phosphorescent polymers (SPPs) as a new class of solution-processable electroluminescent emitters have been first synthesized by efficient non-bonding assembly between bis(dibenzo-24-crown-8)-functionalized iridium complex monomers and bis(dibenzylammonium)-tethered co-monomers. These SPPs display good film morphology and high glass transition temperatures. The OLED device with a configuration of ITO/PEDOT:PSS/SPPs/CsF/Al exhibited a maximum luminous efficiency of 3.91 cd A−1 with the Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.42), as the concentration of the monomer (FPyCr)2Irpic is 1 mol%. This approach is promising for realization of solution-processable all-phosphorescent materials for white organic light-emitting diodes.
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