Amperometric ascorbic acid biosensor based on carbon nanoplatelets derived from ground cherry husks

Amperometric ascorbic acid biosensor based on carbon nanoplatelets derived from ground cherry husks
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基于源自磨碎樱桃壳的碳纳米片的电流抗坏血酸生物传感器

DOI:
10.1016/j.elecom.2017.08.007
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发表时间:
2017-09
影响因子:
5.4
通讯作者:
Ming Zhou
Ming Zhou
中科院分区:
工程技术3区
文献类型:
--
作者:
Xiuxiu Li;Yuanhong Wang;Jingju Liu;Mimi Sun;Xiangjie Bo;Hsing-Lin Wang;Ming Zhou

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In this work, a novel amperometric biosensor based on carbon nanoplatelets derived from ground cherry (Physalis peruviana) husks (GCHs-CNPTs) is reported for the sensitive and selective detection of ascorbic acid (AA). The structure of the nanoplatelets, the oxygen-containing groups and edge-plane-like defective sites (EPDSs) on the GCHs-CNPTs were characterized by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The presence of GCHs-CNPTs with a high density of EPDSs effectively enhances the electron transfer between AA and the glassy carbon electrode (GCE), and thus induces a substantial decrease in the overvoltage for AA oxidation compared with both a bare GCE and a GCE modified with carbon nanotubes (CNTs/GCE). In particular, an amperometric biosensor based on GCHs-CNPTs exhibited a wider linear range (0.01–3.57 mM), higher sensitivity (208.63 μA mM− 1cm− 2), a lower detection limit (1.09 μM, S/N = 3) and better resistance to fouling for AA determination compared to a CNTs/GCE. The great potential of the GCHs-CNPTs/GCE for practical and reliable AA analysis was demonstrated by the successful determination of AA in samples taken from a medical injection dose and a soft drink.
DOI: --
发表时间: 2016
期刊: --
影响因子: --
作者:
Guo Jinzhi;Wand Fang;Wu Xinglong;Zhang Jingping
通讯作者: Guo Jinzhi;Wand Fang;Wu Xinglong;Zhang Jingping
DOI: 10.1002/cctc.201500198
发表时间: 2015-09
期刊: ChemCatChem
影响因子: 4.5
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影响因子: --
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