The Optical Activity of Polypeptides in far Ultraviolet

The Optical Activity of Polypeptides in far Ultraviolet
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多肽的远紫外光学活性

DOI:
10.1021/ja00875a039
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发表时间:
1962
影响因子:
15
通讯作者:
P. Doty
P. Doty
中科院分区:
化学1区
文献类型:
--
作者:
G. Holzwarth;W. Gratzer;P. Doty

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(13)见例子XV。库恩,这是安。RET。太棒了。化学,9,417(1958)。225微米棉花效应的消光系数大于190微米棉花效应的消光系数,尽管190微米棉花效应观察到的旋转大小要大几倍。最后应该指出的是,到目前为止,还不可能获得低于184微米的可靠测量结果,但我们的数据外推表明,190微米棉花效应的低谷应该在175微米到182微米之间。进一步的细节和其他材料的结果将在适当的时候公布。
(13) See for example XV. Kuhn, Ann. Ret. Phys. Chem., 9, 417 (1958). the extinction coefficient is larger for the 225 µ Cotton effect than for the 190 µ Cotton effect, although the size of the rotations observed with the 190 µ Cotton effect is severalfold greater. Finally it should be noted that as yet it has not been pos-sible to obtain reliable measurements below 184 µ but extrapolation of our data indicate that the trough of the 190 µ Cotton effect should be be-tween 175 and 182 µ. Further details and re-sults with other materials will be published in due course.