CO2 Hydrogenation to Methanol over Copper Catalysts: Learning from Syngas Conversion

CO2 Hydrogenation to Methanol over Copper Catalysts: Learning from Syngas Conversion
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铜系催化剂上CO2加氢制甲醇的研究进展

DOI:
10.1007/s11244-021-01427-y
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发表时间:
2021-03-25
影响因子:
3.6
通讯作者:
Burch, Robbie
Burch, Robbie
中科院分区:
化学4区
文献类型:
--
作者:
Golunski, Stan;Burch, Robbie

文献摘要

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许多关于合成气在Cu/ZnO/Al2O3催化剂上合成甲醇的基本原理的开创性工作是由Spencer和他的同事完成的。他们的工作涉及与反应机制和活性位点性质有关的关键问题。这些研究的发现,其中许多已经通过现代计算和实验技术得到验证和改进,现在正在为二氧化碳加氢制甲醇利用催化剂系统的选择和设计提供信息。
Much of the seminal work on the fundamentals of methanol synthesis from syngas over Cu/ZnO/Al2O3 catalysts was carried out by Spencer and co-workers. Their work addressed key questions relating to the reaction mechanism and the nature of the active sites. The findings of these studies, many of which have since been validated and refined using modern computational and experimental techniques, are now informing the selection and design of catalyst systems for CO2 utilisation by hydrogenation to methanol.