A Bench-Stable Pd Catalyst for the Hydroarylation of Fullerene with Boronic Acids
A Bench-Stable Pd Catalyst for the Hydroarylation of Fullerene with Boronic Acids
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DOI：
10.1021/ol801936j
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发表时间：
2008-10-16
期刊：
影响因子：
5.2
通讯作者：
Itami, Kenichiro
中科院分区：
文献类型：
--
作者：
Mori, Susumu;Nambo, Masakazu;Itami, Kenichiro
提出了一种用于富勒烯与硼酸加氢芳基化的 Pd(II) 催化剂。在催化量的 Pd(2-PyCH=NPh)(OCOC6F5)(2) 存在下，在 H2O/1,2-Cl2C6H4 中于室温下用芳基硼酸处理 C-60，以良好的收率和高选择性提供加氢芳基化产物 (Ar-C-60-H)。该配合物具有高催化活性以及固态的工作台稳定性。
A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C-60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh)(OCOC6F5)(2) in H2O/1,2-Cl2C6H4 at room temperature furnishes the hydroarylation product (Ar-C-60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.