Synthesis and structural characterization of Ln(III) complexes (Ln = Eu, Gd, Tb, Er, Tm, Lu) of tripodal tris[2-(salicylideneamino)ethyl]amine
Synthesis and structural characterization of Ln(III) complexes (Ln = Eu, Gd, Tb, Er, Tm, Lu) of tripodal tris[2-(salicylideneamino)ethyl]amine
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DOI：
10.1246/cl.1999.137
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发表时间：
1999-02-01
影响因子：
1.6
通讯作者：
Yokoyama, T
中科院分区：
文献类型：
--
作者：
Kanesato, M;Yokoyama, T
本文研究了七齿（N_4O_3）配体Trensal三[2-（水杨醛氨基）乙基]胺（H_3L_1）的Ln（Ⅲ）配合物（Ln = Eu，Gd，Tb，Er，Tm，Lu）的合成与表征。[LnL（1）]的分子结构通过X射线结构分析确定;这些是七齿配合物，其中金属离子由三个氧原子和四个氮原子配位。
The preparation and characterization of Ln(III) complexes (Ln = Eu, Gd, Tb, Er, Tm, Lu) of heptadentate (N4O3) ligand trensal, tris[2-(salicylideneamino)ethyl]amine (H3L1), have been studied. The molecular structures of [LnL(1)] were determined by X-ray structural analysis; these are heptadentate complexes in which the metal ions are coordinated by the three oxygen atoms and the four nitrogen atoms.