Polymerization of Azastyrene Derivatives. 3.† Preparation and Polymerization of N-Methyleneaniline

Polymerization of Azastyrene Derivatives. 3.† Preparation and Polymerization of N-Methyleneaniline
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Aga苯乙烯衍生物的聚合 3.† N-亚甲基苯胺的制备和聚合。

DOI:
10.1021/ma9709415
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发表时间:
1998
期刊:
影响因子:
5.5
通讯作者:
M. Kamachi
M. Kamachi
中科院分区:
化学1区
文献类型:
--
作者:
A. Hashidzume;A. Kajiwara;A. Harada;M. Kamachi

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N-亚甲基苯胺与乙酸或正丁基锂在四氢呋喃(THF)中聚合得到聚合物[CH 2N(Ph)] n。该聚合物为结晶性,不溶于多种溶剂,在10200 °C下分解形成单体
The polymer [CH 2 N(Ph)] n was obtained by the polymerization of N-methyleneaniline with acetic acic or n-BuLi in THF. The polymer was crystalline, insoluble in many solvents and decomposed at ∼200°C to form the monomer