An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}.
An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}.
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DOI：
10.1039/c2dt32364h
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发表时间：
2013-01
影响因子：
4
通讯作者：
Han-Rui Tian;Wen‐Hua Wang;Xiao-ping Zhang;Yun-long Feng;Jian-Wen Cheng
中科院分区：
文献类型：
--
作者：
Han-Rui Tian;Wen‐Hua Wang;Xiao-ping Zhang;Yun-long Feng;Jian-Wen Cheng
在温和水热条件下，以B(6)O(14)(OH) {B(6)}和Pb(6)O(5)(OH) {Pb(6)}为簇构单元，合成了新型三维硼酸铅Pb(6)B(6)O(14)(OH)(2)（H(2)O）。每个{B(6)}簇与7个{Pb(6)}簇相连，反之亦然，形成第一个7连接的硼酸铅网络。
A new 3D lead borate Pb(6)B(6)O(14)(OH)(2)(H(2)O), built by different cluster building units of B(6)O(14)(OH) {B(6)} and Pb(6)O(5)(OH) {Pb(6)}, has been obtained under mild hydrothermal conditions. Each {B(6)} cluster is linked with seven {Pb(6)} clusters and vice versa that give rise to the first 7-connected lead borate network.