Influence of graphene microstructures on electrochemical performance for supercapacitors

Influence of graphene microstructures on electrochemical performance for supercapacitors
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DOI:
10.1016/j.pnsc.2015.10.004
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发表时间:
2015-10-01
影响因子:
4.7
通讯作者:
Pan, Chunxu
Pan, Chunxu
中科院分区:
材料科学2区
文献类型:
--
作者:
Gong, Youning;Li, Delong;Pan, Chunxu

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采用SEM、FTIR和拉曼光谱、循环伏安(CV)、恒流充放电和电化学阻抗谱(EIS)等测试手段,比较系统地研究了不同石墨烯对超级电容器电化学性能的影响。结果显示:1)在相同的电压扫描速率下,氮掺杂石墨烯(N-G)电极的比电容最高,在1A/g下,N-G电极的比电容达到243.5F/g,而常规氧化石墨(GO)和还原氧化石墨烯(rGO)的比电容分别为43.5F/g和67.9F/g; 3)N-G具有最好的超级电容性能和优越的上级电化学性能,是一种理想的超级电容器电极材料。(C)2015中国材料研究会。由爱思唯尔公司制作和主持
The influence of variant graphenes on electrochemical performance for supercapacitors was studied comparatively and systematically by using SEM, FTIR and Raman spectroscopy, cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS). The results revealed that: 1) the nitrogen-doped graphene (N-G) electrode exhibited the highest specific capacitance at the same voltage scan rate; 2) the specific capacitance of the N-G reached up to 243.5 F/g at 1 A/g, while regular graphite oxide (GO) was 43.5 F/g and reduced graphene oxide (rGO) was 67.9 F/g; 3) N-G exhibited the best supercapacitance performance and the superior electrochemical properties, which made it an ideal electrode material for supercapacitors. (C) 2015 Chinese Materials Research Society. Production and hosting by Elsevier B.V.