Robust hydrogen-bonded self-assemblies from biimidazole complexes. Synthesis and structural characterization of [M(biimidazole)2(OH2)2]2+ (M = Co2+, Ni2+) complexes and carboxylate modules.
Robust hydrogen-bonded self-assemblies from biimidazole complexes. Synthesis and structural characterization of [M(biimidazole)2(OH2)2]2+ (M = Co2+, Ni2+) complexes and carboxylate modules.
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DOI：
10.1039/b312541f
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发表时间：
2004-02
影响因子：
4
通讯作者：
R. Atencio;M. Chacón;T. González;A. Briceño;Giuseppe Agrifoglio;A. Sierraalta
中科院分区：
文献类型：
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作者：
R. Atencio;M. Chacón;T. González;A. Briceño;Giuseppe Agrifoglio;A. Sierraalta
利用一种强健的异质氢键合子[R2(2) (9)-Id]驱动四种配位配合物[M(H2biim)2(OH2)2]2+ (M = Co2+, Ni2+)和羧酸盐反离子的模块化自组装。这种策略使我们能够构建0、1和2维的分子结构。设计了一种具有空腔的氢键二维网络，该网络在可逆的解吸-再吸收过程中保持了惊人的完整性。
A robust heteromeric hydrogen-bonded synthon [R2(2) (9)-Id] is exploited to drive the modular self-assembly of four coordination complexes [M(H2biim)2(OH2)2]2+ (M = Co2+, Ni2+) and carboxylate counterions. This strategy allowed us to build molecular architectures of 0-, 1-, and 2-dimensions. A hydrogen-bonded 2D-network with cavities has been designed, which maintains its striking integrity after reversible water desorption-resorption processes.