Tetrahedral-atom 3-ring groupings in 1-dimensional inorganic chains: beryllium arsenate hydroxide hydrate (Be2AsO4OH.cntdot.4H2O) and sodium zinc hydroxide phosphate hydrate (Na2ZnPO4OH.cntdot.7H2O)
Tetrahedral-atom 3-ring groupings in 1-dimensional inorganic chains: beryllium arsenate hydroxide hydrate (Be2AsO4OH.cntdot.4H2O) and sodium zinc hydroxide phosphate hydrate (Na2ZnPO4OH.cntdot.7H2O)
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一维无机链中的四面体原子 3 环基团：砷酸铍氢氧化物水合物 (Be2AsO4OH.cntdot.4H2O) 和氢氧化钠磷酸锌水合物 (Na2ZnPO4OH.cntdot.7H2O)
DOI：
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发表时间：
1993
期刊：
影响因子：
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通讯作者：
G. Stucky
中科院分区：
文献类型：
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作者：
W. Harrison;T. Nenoff;T. E. Gier;G. Stucky
报道了Be 2 AsO 4 OH.4H 2 O和Na 2 ZnPO 4 OH.7H 2 O的水热合成和X射线单晶结构，这两个相含有三环四面体作为MXO 4 (M=Zn，Be；X=P，As)基团一维链的一部分。报告了这些相的 MAS NMR 和 TGA 数据，并将这两种材料的结构与其他一些已知的扩展四面体物质的结构进行了简要比较。
The hydrothermal syntheses and X-ray single-crystal structures of Be 2 AsO 4 OH.4H 2 O and Na 2 ZnPO 4 OH.7H 2 O, two phases which contain 3-ring groupings of tetrahedra as part of 1-dimensional chains of MXO 4 (M=Zn, Be; X=P, As) groups, are reported. MAS NMR and TGA data are reported for these phases, and the structures of these two materials are briefly compared with those of some other known extended tetrahedral species.