Selective pure-phase synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family.
Selective pure-phase synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family.
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DOI：
10.1021/ja108965s
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发表时间：
2010-11
影响因子：
15
通讯作者：
Sun Woo Kim;H. Chang;P. Halasyamani
中科院分区：
文献类型：
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作者：
Sun Woo Kim;H. Chang;P. Halasyamani
发现了一种低温、高产率的水热合成多铁性BaMF（4）（M = Mg、Mn、Co、Ni和Zn）族化合物的纯相路线。合成涉及在水介质中使用CF（3）COOH代替HF，并且在正确的条件下，产生纯的多晶BaMF（4）。除了合成的描述，二次谐波产生，热重和差示扫描量热法的数据。
A low temperature, high yield hydrothermal route has been discovered for the phase-pure synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family. The synthesis involves the use of CF(3)COOH instead of HF in an aqueous medium and, under the correct conditions, produces pure and polycrystalline BaMF(4). In addition to the synthetic description, second-harmonic generation, thermogravimetric, and differential scanning calorimetry data are presented.