Ion-Transfer Voltammetry at a Polarized Room-Temperature Molten Salt | Water Interface
Ion-Transfer Voltammetry at a Polarized Room-Temperature Molten Salt | Water Interface
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极化室温熔盐的离子转移伏安法|
DOI：
10.2116/analsci.19.651
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发表时间：
2003
影响因子：
1.6
通讯作者：
Hirosuke Tatsumi
中科院分区：
文献类型：
--
作者：
H. Katano;Hirosuke Tatsumi
四辛基铵阳离子与 2,4,6-三硝基苯酚阴离子形成室温熔盐 (RTMS)。 RTMS 与水 (W) 不混溶并形成稳定的 RTMS | W接口。事实证明，RTMS | W界面可以电化学极化。由于硫氰酸根离子穿过 RTMS 的转移而产生清晰的伏安波 |在电位窗口内观察到W界面。这是极化 RTMS 的第一个示例 | W接口。
Tetraoctylammonium cation forms a room-temperature molten salt (RTMS) with 2,4,6-trinitrophenolate anion. The RTMS is immiscible with water (W) and forms a stable RTMS | W interface. It has been shown that the RTMS | W interface can be electrochemically polarized. A well-defined voltammetric wave due to the transfer of thiocyanate ion across the RTMS | W interface was observed within the potential window. This is the first example of a polarized RTMS | W interface.
影响因子：
5.4
作者：
Kakiuchi, T;Tsujioka, N;Iwami, Y
通讯作者：
Iwami, Y