Oxide Electrolytes for Lithium Batteries
Oxide Electrolytes for Lithium Batteries
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DOI：
10.1111/jace.13844
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发表时间：
2015-12-01
影响因子：
3.9
通讯作者：
Nan, Ce-Wen
中科院分区：
文献类型：
--
作者：
Ren, Yaoyu;Chen, Kai;Nan, Ce-Wen
高锂离子电导率氧化物电解质是未来锂电池最有希望的固体电解质材料，在过去的几十年里得到了迅速的发展。现有的氧化物电解质分为两组，即，晶体组包括NASICON、钙钛矿、石榴石和一些新发展的结构，以及非晶/玻璃组包括Li 2 O-MOx（M = Si、B、P等）。和LiPON相关的材料。在回顾了氧化物电解质发展的历史之后，对高锂离子电导率氧化物电解质进行了综述，重点介绍了锂离子电池固体电解质的材料选择和设计。介绍了氧化物电解质在锂电池中应用的一些成功实例和有意义的尝试。在结论部分，对氧化物电解质的发展方向进行了展望。
As the most promising candidate of the solid electrolyte materials for future lithium batteries, oxide electrolytes with high-lithium- ion conductivity have experienced a rapid development in the past few decades. Existing oxide electrolytes are divided into two groups, i.e., crystalline group including NASICON, perovskite, garnet, and some newly developing structures, and amorphous/glass group including Li2O-MOx (M = Si, B, P, etc.) and LiPON-related materials. After a historical perspective on the general development of oxide electrolytes, we try to give a comprehensive review on the oxide electrolytes with high-lithium-ion conductivity, with special emphasis on the aspect of materials selection and design for applications as solid electrolytes in lithium batteries. Some successful examples and meaningful attempts on the incorporation of oxide electrolytes in lithium batteries are also presented. In the conclusion part, an outlook for the future direction of oxide electrolytes development is given.