Selective formation of a stable μ-peroxo ferric heme-CuII complex from the corresponding μ-oxo FeIII-CuII species with hydrogen peroxide
Selective formation of a stable μ-peroxo ferric heme-CuII complex from the corresponding μ-oxo FeIII-CuII species with hydrogen peroxide
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DOI：
10.1039/b413275k
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发表时间：
2005-02-28
影响因子：
4.9
通讯作者：
Naruta, Y
中科院分区：
文献类型：
--
作者：
Chishiro, T;Shimazaki, Y;Naruta, Y
的氧桥铁血红素-铜（II）的配合物，通过相应的过氧桥的配合物的热转化得到的，与等摩尔量的H2 O2反应，以再生的p-过氧，配合物通过从氧到过氧的配体交换，而不形成一个铁基氧物种或血红素降解中观察到的一般铁血红素-H2 O2反应。
An oxo-bridged ferric heme-copper(II) complex, obtained by thermal transformation of the corresponding peroxo-bridged complex, was reacted with an equimolar amount of H2O2 to regenerate the p-peroxo, complex by a ligand exchange from oxo to peroxo, without the formation of a ferryl-oxo species or heme degradation as are observed in general ferric heme-H2O2 reactions.