Metal-peptide frameworks (MPFs):: "Bioinspired" metal organic frameworks
Metal-peptide frameworks (MPFs):: "Bioinspired" metal organic frameworks
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DOI：
10.1021/ja0762588
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发表时间：
2008-02-27
影响因子：
15
通讯作者：
Taubert, Andreas
中科院分区：
文献类型：
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作者：
Mantion, Alexandre;Massuger, Lars;Taubert, Andreas
手性金属有机框架（MOFs）因其在能源技术、不对称催化、手性分离以及在更基本的层面上，在无机材料中创造新的拓扑结构方面的潜在用途而引起了人们越来越多的兴趣。这篇论文是关于基于肽的MOF的第一篇报道，这是一种金属肽框架（MPF），由我们的团队早期开发的寡聚缬氨酸肽家族构建而成（Mantion, a .；等）。絮凝。生物科学，2007,7,208)。我们使用了一种简单的寡肽，Z-(L-Val)(2)- l - glu (OH)-OH，来生长多孔铜和钙的MPFs。MPFs的形成是由于微粒的自组装特性和特定的金属-肽和金属-氨相互作用。它们在高达约250摄氏度的温度下是稳定的，并且具有一定的内部孔隙率，这使它们成为mpf进一步发展的有希望的原型。
Chiral metal-organic frameworks (MOFs) have attracted a growing interest for their potential use in energy technologies, asymmetric Catalysis, chiral separation, and on a more basic level, the creation of new topologies in inorganic materials. The current paper is the first report on a peptide-based MOF, a metal peptide framework (MPF), constructed from an oligovaline peptide family developed earlier by our group (Mantion, A.; et al. Macromol. Biosci. 2007, 7, 208). We have used a simple oligopeptide, Z-(L-Val)(2)-L-Glu(OH)-OH, to grow porous copper and calcium MPFs. The MPFs form thanks to the self-assembling properties of the pepticle and specific metal-peptide and metal-ammonia interactions. They are stable up to ca. 250 degrees C and have some internal porosity, which makes them a promising prototype for the further development of MPFs.